Patent
Luminescent material made of a polymer-matrix comprising luminescent organic compound and luminescent metal clusters.
S. Khlifi, Y. Molard, M. Achard, M. Amela-Cortes,
Eur. Pat. Appl., n: 19395523.3, 23/04/2019
Nanocomposite material made of a polymer-matrix comprising peo-containing polymers and salts of luminescent polyanionic metal clusters.
Y. Molard, E. Molina, M. Amela-Cortes, M. Robin, S. Cordier,
Eur. Pat. Appl., n: 17306490.8,30/10/2017; PCT Int. Appl. WO2019086477
Luminescent salts with metal cluster anions and organic cations and hybrid polymers with high cluster content.
Y. Molard, M. Amela-Cortes, S. Cordier,
PCT Int. Appl., 2014, WO 2014111435, EP 2754706, US20150344773
A material comprising an host matrix, rare earth ions and a metal atom cluster as sensitizer.
Y. Molard, M. Amela-Cortes, S. Cordier, C. Labbe, J. Cardin, R. Rizk,
PCT Int. Appl., 2014, WO 2014111434 A1 20140724.
Luminescent hybrid liquid crystal,
Y. Molard, S. Cordier, M. Amela-Cortes, F. Dorson,
US Pat. Appl. Publ., 2011,
US20110130565
Publication
last update:11/07/2024
125)"Emissive supramolecular ionic crystals combining a red-NIR phosphorescent [Re6Se8CN6]4− cluster anion and a blue fluorescent tetraphenylethene counter-cation"
I. V. Kashnik; M. Cordier; K. A. Brylev; P.-A. Bouit; S. Cordier; Y. Molard
Dalton Trans. 2024. 10.1039/D4DT01488J
124)"Smart emissive hybrid dynamer and nanocomposite made of complementary organic and inorganic emitters combined via a supramolecular Janus synthon"
I. V. Kashnik; J. Rebours; N. Dumait; K. A. Brylev; Y. Molard
J. Mater. Chem. C 2024, 12, 8398-8407. 10.1039/D4TC01043D
123)"Luminescent Supramolecular Ionic Frameworks based on Organic Fluorescent Polycations and Polyanionic Phosphorescent Metal Clusters"
I. V. Kashnik; B. Yang; S. S. Yarovoi; T. S. Sukhikh; M. Cordier; G. Taupier; K. A. Brylev; P.-A. Bouit; Y. Molard
Chem. Eur. J. 2024, 30 (21), e202400079.
122) "Game of Crowns: Na+ Is Coming! Red NIR-Emissive Hybrid Liquid Crystals Containing Discotic Crown Ethers and Na2Mo6X8iCl6 (Xi = Cl or Br)"
I. Carrasco, P. Ehni, M. Ebert, N. Dumait, G. Taupier, M. Amela-Cortes, C. Roiland, S. Cordier, J. A. Knöller, E. Jacques, S. Laschat, Y. Molard
ACS Appl. Mater. Interfaces 2023, 15 (33), 39752-39764. 10.1021/acsami.3c08441
121)"Asymmetric Ruthenium Catalysis Enables Fluorophores with Point Chirality Displaying CPL Properties"
Y. Sun; K. Dhbaibi; H. Lauwick; C. Lalli; G. Taupier; Y. Molard; R. Gramage-Doria; S. Dérien; J. Crassous; M. Achard
Chem. -Eur. J. 2023, 29 (10), e202203243. 10.1002/chem.202203243
120) "Photoinduced electron transfer between a noble-metal-free [Mo6I8Cl6]2− cluster and polyoxometalates"
A. Fatima, Y. Smortsova, C. Falaise, N. Leclerc, M. Haouas, E. Cadot, S. Cordier, Y. Molard, T. Pino, C. Dablemont, R. Méallet, K. Steenkeste, M.-H. Ha-Thi
Chem. Commun. 2023. 10.1039/D3CC03334A
119) "Synthesis, photophysical characterization, and integration of two-photon-responsive fluorophores in mesoporous organosilica nanoparticles for biological imaging use"
N. Bondon, N. Richy, L. M. A. Ali, D. Durand, M. Gary-Bobo, Y. Molard, G. Taupier, F. Paul, N. Bettache, J.-O. Durand, C. Nguyen, C. Charnay, O. Mongin
Tetrahedron 2023, 144, 133577. https://doi.org/10.1016/j.tet.2023.133577
118) "Electrophilic and nucleophilic gas phase reactivity of the Janus cluster-based anions [{Mo6Cl8}Cl5&] (& = lacuna) "
A. Denis, N. Tyminska, T. Delhaye, Y. Molard, P. Gerbaux, J. De Winter, M. Himdi, X. Castel, K. Costuas, S. Cordier, D. Rondeau
Chem. Commun. 2023, 59, 6243-6246. DOI: 10.1039/D3CC01187A
117) “Luminescent Liquid Crystals: from Supramolecular Plant Dyes to Emissive Flavylium Salts”
R. Forschner, J. A. Knöller, A. Zens, W. Frey, Y. Molard, S. Laschat
Liq. Cryst., 2023, doi: 10.1080/02678292.2023.2179122
116) "Supramolecular host-guest assemblies of [M6Cl14]2–, M = Mo, W, clusters with γ-cyclodextrin"
A. A. Ivanov, P. A. Abramov, M. Haouas, Y. Molard, S. Cordier, C. Falaise, E. Cadot, M. A. Shestopalov
Inorganics, 2023,
115) " Flexible and transparent luminescent cellulose-transition metal cluster composites"
M. Amela-Cortes, N. Dumait, F. Artzner, S. Cordier, Y. Molard, Y., S. Cordier
Nanomaterials 2023, 13, 3, https:// doi.org/10.3390/nano13030580
114) "From Solid-State Cluster Compounds to Functional PMMA-Based Composites with UV and NIR Blocking Properties, and Tuned Hues"
M. Amela-Cortes, M. Wilmet, S. Le Person, S. Khlifi, C. Lebastard, Y. Molard, Y., S. Cordier
Nanomaterials 2023, 13, 144. https:// doi.org/10.3390/nano13010144
113) "Non-Destructive All-Optical Readout Through Photoswitching of Intramolecular Excimer Emission"
M. Barale, M. Escadeillas, G. Taupier, Y. Molard, C. Orione, E. Caytan, R.Métivier, J. Boixel
J. Phys. Chem. Letters, 2022, 13, 47, 10936–10942
112) "Asymmetric Ruthenium Catalysis Enables Fluorophores with Point Chirality Displaying CPL Properties"
Y. Sun, K. Dhbaibi, H. Lauwick, C. Lalli, G. Taupier, Y. Molard, R. Gramage-Doria, S. Dérien, J. Crassous, M. J. Achard
Chem. –Eur. J. 2022, e202203243. https://doi.org/10.1002/chem.202203243
111) "Molybdenum-Iodine Cluster Loaded Polymeric Nanoparticles Allowing a Coupled Therapeutic Action with Low Side Toxicity for Treatment of Ovarian Cancer"
A. Verger, G. Dollo, S. Martinais, Y. Molard, S. Cordier, M. Amela-Cortes, N. Brandhonneur
J. Pharm. Sci. 2022, 111, 3377-3383 https://doi.org/10.1016/j.xphs.2022.09.010
110) "Stabilization of Octahedral Metal Halide Clusters by Host–Guest Complexation with γ-Cyclodextrin: Toward Nontoxic Luminescent Compounds"
A. A. Ivanov, M. Haouas, D. V. Evtushok, T. N. Pozmogova, T. S. Golubeva, Y. Molard, S. Cordier, C. Falaise, E. Cadot, M. A. Shestopalov
Inorg. Chem. 2022, 10.1021/acs.inorgchem.2c02468
109) "Cost-efficient polyurea carrier for precise control of an anti-inflammatory drug loading and release"
G. A. Pedroza, L. H. G. M. C. Macêdo, R. de Oliveira, N. N. Silveira, R. P. Orenha, R. L. T. Parreira, R. A. dos Santos, Y. Molard, M. Amela-Cortes, E. F. Molina
J. Drug Deliv. Sci. Technol. 2022, 76, 103744, https://doi.org/10.1016/j.jddst.2022.103744
108) "Merging liquid crystalline self-assembly and linear optical properties of merocyanines via tailored donor units"
P. Ehni, S. M. Bauch, P. M. Becker, W. Frey, A. Zens, J. Kaestner, Y. Molard, S. Laschat
Phys. Chem. Chem. Phys. 2022, 10.1039/d2cp02237k
107) "Highly Tunable Circularly Polarized Emission of an Aggregation-Induced Emission Dye Using Helical Nano- and Microfilaments as Supramolecular Chiral Templates"
J. Liu, Y. Molard, M. E. Prevot, T. Hegmann
ACS Appl. Mater. Interfaces 2022, 14, 29398-29411, 10.1021/acsami.2c05012
106) "Chasing Self-Assembly of Thioether-Substituted Flavylium Salts in Solution and Bulk State"
J. A. Knoller, R. Forschner, W. Frey, J. Lang, A. Baro, A. Zens, Y. Molard, F. Giesselmann, B. Claasen, S. Laschat
ChemPhysChem 2022, 23, e202200154, 10.1002/cphc.202200154
105) "Straightforward Access to Multifunctional π-Conjugated P-Heterocycles Featuring an Internal Ylidic Bond"
T. Delouche, E. Caytan, M. Cordier, T. Roisnel, G. Taupier, Y. Molard, N. Vanthuyne, B. Le Guennic, M. Hissler, D. Jacquemin, P.-A. Bouit
Angew. Chem., Int. Ed. 2022, 61, e202205548, 10.1002/anie.202205548
104) "Octahedral Molybdenum Cluster-Based Single Crystals as Fabry–Pérot Microresonators"
E. Segura-Sanchis, R. Fenollosa, I. Rodriguez, Y. Molard, S. Cordier, M. Feliz, P. Atienzar
Cryst. Growth Des., 2022, 22 (1), 60-65. https://doi.org/10.1021/acs.cgd.1c01144
103) "Joint Venture of Metal Cluster and Amphiphilic Cationic Minidendron Resulting in NIR Emissive Lamellar Ionic Liquid Crystals"
M. Ebert, I. Carrasco, N. Dumait, W. Frey, A. Baro, A. Zens, M. Lehmann, G. Taupier, S. Cordier, E. Jacques, Y. Molard, S. Laschat
Chem. - Eur. J., 2022, 28 (3), e202103446. https://doi.org/10.1002/chem.202103446
102) "Design of polyurea networks containing anticancer and anti-inflammatory drugs for dual drug delivery purposes"
M. A. de Resende, G. A. Pedroza, L. H. G. M. C. Macêdo, R. de Oliveira, M. Amela-Cortes, Y. Molard, E. F. Molina
J. Appl. Polym. Sci., 2022, 139 (16), 51970. https://doi.org/10.1002/app.51970
101) "From molecules to nanovectors: Current state of the art and applications of photosensitizers in photodynamic therapy"
A. Verger, N. Brandhonneur, Y. Molard, S. Cordier, K. Kowouvi, M. Amela-Cortes, G. Dollo
Int. J. Pharm., 2021, 604, 120763. https://doi.org/10.1016/j.ijpharm.2021.120763
100) "Evidencing ((n-C4H9)4N)2[W6I14] red–NIR emission and singlet oxygen generation by two photon absorption"
Y. Molard, G. Taupier, S. Paofai, S. Cordier
Chem. Commun., 2021, 57, 4003-4006. https://doi.org/10.1039/D1CC00751C
99) "Expanding the Toolbox of Octahedral Molybdenum Clusters and Nanocomposites Made Thereof: Evidence of Two-Photon Absorption Induced NIR Emission and Singlet Oxygen Production"
S. Khlifi, G. Taupier, M. Amela-Cortes, N. Dumait, S. Freslon, S. Cordier, Y. Molard
Inorg. Chem., 2021, 60 (8), 5446-5451. https://doi.org/10.1021/acs.inorgchem.1c00517
98) "Poly(dimethylsiloxane) functionalized with complementary organic and inorganic emitters for the design of white emissive waveguides"
S. Khlifi, J. Bigeon, M. Amela-Cortes, N. Dumait, H. Akdas-Kiliç, G. Taupier, S. Freslon, S. Cordier, S. Derien, M. Achard, G. H. Loas, Y. Molard
J. Mater. Chem. C, 2021, 9, 7094-70102. https://doi.org/10.1039/D1TC01229K
97) "Facile and scalable design of light-emitting and ROS-generating hybrid materials made of polyurea gels embedding a molybdenum cluster-based salt"
N. A. M. de Jesus, R. de Oliveira, M. Amela-Cortes, N. Dumait, S. Cordier, Y. Molard, E. F. Molina
Dalton Trans., 2021, 50 (25), 8907-8916. https://doi.org/10.1039/d1dt00962a
96) "Molybdenum cluster loaded PLGA nanoparticles as efficient tools against epithelial ovarian cancer"
N. Brandhonneur, Y. Boucaud, A. Verger, N. Dumait, Y. Molard, S. Cordier, G. Dollo
Int. J. Pharm., 2021, 592, 120079. https://doi.org/10.1016/j.ijpharm.2020.120079
95) "Self-erasable inkless imprinting using a dual emitting hybrid organic-inorganic material"
S. Khlifi, N. Fournier Le Ray, S. Paofai, M. Amela-Cortes, H. Akdas-Kilic, G. Taupier, S. Derien, S. Cordier, M. Achard, Y. Molard
Mater. Today, 2020, 35, 34-41. https://doi.org/10.1016/j.mattod.2019.12.002
94) "Cyclodextrin-Assisted Hierarchical Aggregation of Dawson-type Polyoxometalate in the Presence of {Re6Se8} Based Clusters"
A. A. Ivanov, C. Falaise, A. A. Shmakova, N. Leclerc, S. Cordier, Y. Molard, Y. V. Mironov, M. A. Shestopalov, P. A. Abramov, M. N. Sokolov, M. Haouas, E. Cadot
Inorg. Chem., 2020, 59 (16), 11396-11406. https://doi.org/10.1021/acs.inorgchem.0c01160
93) "From supramolecular to solid state chemistry: crystal engineering of luminescent materials by trapping molecular clusters in an aluminium-based host matrix"
C. Falaise, A. A. Ivanov, Y. Molard, M. Amela Cortes, M. A. Shestopalov, M. Haouas, E. Cadot, S. Cordier
Mater. Horiz., 2020, 7 (9), 2399-2406. https://doi.org/10.1039/d0mh00637h
92) "Fluorenone imidazolium salts as novel de Vries materials"
K. Bader, C. Mueller, Y. Molard, A. Baro, P. Ehni, J. Knelles, S. Laschat
RSC Adv., 2020, 10 (40), 23999-24016. https://doi.org/10.1039/d0ra04650g
91) Switchable Two-Dimensional Waveguiding Abilities of Luminescent Hybrid Nanocomposites for Active Solar Concentrators
S. Khlifi, J. Bigeon, M. Amela-Cortes, N. Dumait, G. h. Loas, S. Cordier, Y. Molard
ACS Applied Materials & Interfaces, 2020, 12 (12), 14400-14407
90) PLGA nanoparticles embedding molybdenum cluster salts: Influence of chemical composition on physico-chemical properties, encapsulation efficiencies, colloidal stabilities and in vitro release
G. Dollo, Y. Boucaud, M. Amela-Cortes, Y. Molard, S. Cordier, N. Brandhonneur
Int. J. Pharmaceutics, 2020, 576, 119025
89) Porosity-driven Large Amplitude Dynamics for Nitroaromatics Sensing with Fluorescent Films of Alternated D-pi-A Molecules
J. P. Malval, M. Cranney, S. Achelle, H. Akdas-Kilig, J.-L. Fillaut, N. Cabon, F. Le Guen, O. Soppera, Y. Molard
Chem. Commun., 2019, 55, 14331-14334
88) Supramolecular Anchoring of Octahedral Molybdenum Clusters onto Graphene and their Synergies in the Photocatalytic Water Reduction
M. Feliz, P. Atienzar, M. Amela-Cortes, N. Dumait, P. Lemoine, Y. Molard, S. Cordier
Inorg. Chem., 2019, 58 (22), 15443-15454
87) When a red NIR emissive Cs2[Mo6Br14] interacts with an active diureasil-PEO matrix: design of tunable and white light emitting hybrid material
A. Ferreira Molina, N. Aparecida Martins de Jesus, S. Paofai, P. Hammer, M. Amela-Cortes, M. Robin, S. Cordier, Y. Molard
Chem. Eur. J., 2019, 25 (67), 15248-15251
86) Size-Exclusion Mechanism Driving Host-Guest Interactions 2 between Octahedral Rhenium Clusters and Cyclodextrins
A. A. Ivanov, C. Falaise, K. Laouer, F. Hache, P. Changenet, Y. V. Mironov, D. Landy, Y. Molard, S. Cordier, M. A. Shestopalov, M. Haouas, E. Cadot
Inorg. Chem., 2019, 58,13184-13194
85) Flavylium salts: A blooming core for bioinspired ionic liquid crystals
R. Forschner, J. Knelles, K. Bader, C. Müller, W. Frey, A. Köhn, Y. Molard, F. Giesselmann, S. Laschat
Chem. Eur. J., 2019, 25, 12966-12980
84) Octahedral molybdenum cluster as a photoactive antimicrobial additive to a fluoroplastic
N. A. Vorotnikova, A. Y. Alekseev, Y. A. Vorotnikov, D. V. Evtushok, Y. Molard, M. Amela-Cortes, S. Cordier, A. I. Smolentsev, C. G. Burton, P. M. Kozhin, P. Zhu, P. D. Topham, Y. V. Mironov, M. Bradley, O. A. Efremova and M. A. Shestopalov
Mater. Sci. Eng. C, 2019, 110150
83) Self-Assembly and Fluorescence of Tetracationic Liquid Crystalline Tetraphenylethene
J. Knelles, S. Beardsworth, K. Bader, J. R. Bruckner, A. Buehlmeyer, R. Forschner, K. Schweizer, W. Frey, F. Giesselmann, Y. Molard, S. Laschat
ChemPhysChem, 2019, 20 (17), 2210-2216
82) Red-NIR luminescence of self-assembled Mo6 inorganic cluster monolayer on Au(001)
M. Kepenekian, Y. Molard,K. Costuas,P. Lemoine,R. Gautier,S. Ababou-Girard,B. Fabre,P. Turban,S. Cordier
Mater. Horiz., 2019, 6, 1828-1833.
81) Novel Luminescent Diazafluorenone Liquid Crystals
K. Bader, R. Gündemir, W. Frey, P. Ehni, Y. Molard, A. Baro, S. Laschat,
Cryst. growth Des., 2019, 19 (8), 4436-4452.
80)Transparent functional nanocomposite films based on octahedral metal clusters: synthesis by electrophoretic deposition process and characterization
Thi Kim Nguyen, N.; Dubernet, M.; Matsui, Y.; Wilmet, M.; Shirahata, N.; Rydzek, G.; Dumait, N.; Amela-Cortes, M.; Renaud, A.; Cordier, S.; Molard, Y.; Grasset, F.; Uchikoshi, T.
Royal Society Open Science, 2019, 6 (3), 181647
79) Modulation of phosphine sulfonate ligands containing copper complexes emission properties: playing with solvato-, thermo-, and mechanochromism
A. Vacher, A. Amar, F. Camerel, Y. Molard, C. Latouche, T. Roisnel, V. Dorcet, A. Boucekkine, H. Akdas-Kilig, M. Achard
Dalton Transactions, 2019, 48(6), 2128-2134
78) The Ouzo Effect to Selectively Assemble Molybdenum Clusters into Nanomarbles or Nanocapsules with Increased HER Activity
F. Sciortino, J. Cuny, F. Grasset, C. Lagrost, P. Lemoine, A. Moréac, Y. Molard, T. Takeie, S. Cordier, S. Chevance, F. Gauffre
Chem. Commun., 2018, 54, 13387-13390
77) Luminescent Liquid Crystalline Hybrid Materials by Embedding Octahedral Molybdenum Cluster Anions with Soft Organic Shells Derived from Tribenzo[18]crown-6
P. Ehni, K. Guy, M. Ebert, S. Beardsworth, K. Bader, R. Forschner, A. Bühlmeyer, N. Dumait, C. Roiland, Y. Molard, S.Laschat
Dalton Transactions, 2018, 47(40), 1430-14351
76) Lord of The Crowns: A New Precious In The Kingdom of Clustomesogens
K. Guy, P. Ehni, S. Paofai, C. Roiland, M. Amela-Cortes, S. Cordier, S. Laschat, Y. Molard
Angew. Chem. Int. Ed., 2018, 57, 11692-11696
75) Ionic Columnar Clustomesogens: Associations between Anionic Hexanuclear Rhenium Clusters and Liquid Crystalline Triphenylene Tethered Imidazoliums
F. Camerel, F. Kinloch, O. Jeannin, M. Robin, S. K. nayak, E. Jacques, K. Brylev, N. G. Naumov, Y. Molard
Dalton Transactions, 2018, 47, 10884-10896
74) Host-Guest Binding Hierarchy within Redox- and Luminescence Responsive Supramolecular Self-Assembly Based on Chalcogenide Clusters and γ-Cyclodextrin
A. A. Ivanov, C. Falaise, P. A. Abramov, M. A. Shestopalov, K. Kirakci, K. Lang, M. A. Moussawi, M. N. Sokolov, N. G. Naumov, S.Floquet, D. Landy, M. Haouas, K. A. Brylev, Y. V. Mironov, Y. Molard, S. Cordier, E. Cadot
Chem. Eur. J., 2018, 24, 11467-11478
73) Direct Integration of Red-NIR Emissive Ceramic-like AnM6Xi8Xa6 Metal Cluster Salts in Organic Copolymers Using Supramolecular Interactions
M. Robin, N. Dumait, M. Amela-Cortes, C. Roiland, M. Harnois, E. Jacques, H. Folliot, Y. Molard
Chem. Eur. J., 2018, 24, 4825-4829
72) Tailoring self-assembling abilities in functional hybrid nanomaterials: from rod-like to disk-like clustomesogens based on a luminescent {Mo6Br8}4+ inorganic cluster core
A.Gandubert, M. Amela-Cortes, S. K. Nayak, C. Vicent, C. Meriadec, F. Artzner, S. Cordier, Y. Molard
J. Mater. Chem. C, 2018, 6, 2556-2564
71) Molybdenum cluster loaded PLGA nanoparticles: an innovative theranostic approach for the treatment of ovarian cancer
N. Brandhonneur, T. Hatahet, M. Amela-Cortes, Y. Molard, S. Cordier, G. Dollo
Eur. J. Pharm. Biopharm., 2018, 125C, 95-105
70) Stabilization of Ni(2+) dimers in hexacyano Mo6 cluster-?based Prussian blue derivatives: experimental and theoretical investigations of magnetic properties
G. Daigre, K. Costuas, M. S. Tarasenko, A. Y. Ledneva, N. G. Naumov, P. Lemoine, T. Guizouarn, Y. Molard, M. Amela-Cortes, N. Audebrand, S. Cordier
Dalton Transactions, 2018, 47, 4, 1122-1130
69) Morphological impact of insulator on inkjet-printed transistor
S. J. Moon, M. Robin, W. Kuai, Y. Molard, B. S. Bae, T. Mohammed-Brahim, E. Jacques, M. Harnois
Flexible and Printed Electronics, 2017, 2, 035008.
68) Polyurethanes prepared from cyclocarbonated broccoli seed oil (PUcc): New biobased organic matrices for incorporation of phosphorescent metal nanocluster
P. Loulergue, M. Amela-Cortes, S. Cordier, Y. Molard, L. Lemiegre, J.-L. Audic
Journal of Applied Polymer Science, 2017, 134, 45, doi: 10.1002/app.45699
67) Mo6 cluster-based compounds for energy conversion applications: comparative study of photoluminescence and cathodoluminescence
B. Dierre, F. Grasset, N. Ohashi, T. Uchikoshi, K. Costuas, N. Dumait, S. Paofai, M. Amela-Cortes, Y. Molard, S. Cordier, Y. Cho , K. Takahashi
Science and technology of advanced materials, 2017, 18, 1, 458-466
66) Improvement of n-type OTFT electrical stability by gold electrode modification
M. Robin, M. Harnois, Y. Molard, E. Jacques
Org Electron, 2016, 39, 214 - 221
65) Time-Gated Luminescence Bioimaging with new Luminescent Nanocolloids based on [Mo6I8(C2F5COO)6]2- Metal Atom Clusters
C. Neaime, M. Amela-Cortes, F. Grasset, Y. Molard, S. Cordier, B. Dierre, M. Mortier, T. Takei, K. Takahashi, H. Haneda, M. Verelst, S. Lechevallier
Phys. Chem. Chem. Phys., 2016, DOI: 10.1039/C6CP05290H
64) Clustomesogens: Liquid Crystalline Hybrid Nanomaterials Containing Functional Metal Nanoclusters
Y. Molard
Acc. Chem. Res., 2016, 49, 8, 1514 - 1523
63) Visible tunable lighting system based on polymer composites embedding ZnO and metallic clusters: from colloids to thin films
T.-G. Truong, B. Dierre, F. Grasset, N. Saito, N. Saito, T. K. N. Nguten, K. Takahashi, T. Uchikoshi, M. Amela-Cortes, Y. Molard, S. Cordier, N. Ohashi
Sci. Tech. Adv. Mater., 2016, 17:1, 443 - 453
62) In Situ Generation of Active Molybdenum Octahedral Clusters for Photocatalytic Hydrogen Production from Water
M. Feliz, M. Puche, P. Atienzar, P. Concepcion, S. Cordier, Y. Molard
ChemSusChem, 2016, 9, 15, 1963 - 1971
61) Efficient active waveguiding properties of Mo 6 nano-cluster-doped polymer nanotubes
J. Bigeon, N. Huby, M. Amela-Cortes, Y. Molard, A. Garreau, S. Cordier, B. Bê,che, J.-L. Duvail,
Nanotechnology, 2016, 27, 25, 255201
60) Elaboration, Characterizations and Energetics of Robust Mo 6 Cluster-Terminated Silicon-Bound Molecular Junctions
S. Cordier, B. Fabre, Y. Molard, A.-B. Fadjie-Djomkam, P. Turban, S. Tricot, S. Ababou-Girard, C. Godet
J. Phys. Chem. C, 2016, 120, 4, 2324 - 2334
59) Phosphorescent columnar hybrid material containing polyionic inorganic nanoclusters
S. K. Nayak, M. Amela-Cortes, M. M. Neidhardt, S. Beardsworth, J. Kirres, M. Mansueto, S. Cordier, S. Laschat, Y. Molard
Chem. Commun., 2016, 52, 3127 - 3130
58) Facile design of red-emitting waveguides using hybrid nanocomposites made of inorganic clusters dispersed in SU8 photoresist host
N. Huby, J. Bigeon, Q. Lagneaux, M. Amela-Cortes, A. Garreau, Y. Molard, J. Fade, A. Desert, E. Faulques, B. Bê,che, J.-L. Duvail, S. Cordier
Optical Materials, 2016, 52, 196-202
57) Preparation of colloidal solution of silica encapsulating cyanobiphenyl units-capped ZnO QD emitting in the blue region
C. Neaime, M. Amela-Cortes, F. Grasset, M. Zakhour, Y. Molard
Dalton Trans., 2016, 45, 886-890
56) Versatility of the Ionic Assembling Method to Design Highly Luminescent PMMA Nanocomposites Containing [M6Qi8La6]n- Octahedral Nano-building Blocks
M. Amela-Cortes, Y. Molard, S. Paofai, A. Desert, J.-L. Duvail, N. G. Naumov, S. Cordier
Dalton Trans., 2016, 45, 237-245
55) Epoxy based ink as versatile material for inkjet-printed devices.
M. Robin, W. Kuai, M. Amela-Cortes, S. Cordier, Y. Molard, T. Mohammed-Brahim, E. Jacques, M. Harnois
ACS Appl. Mater. Interfaces, 2015, 7, 39, 21975 - 21984
54) Combined theoretical and time-resolved photoluminescence investigations of [Mo6Bri8Bra6]2- metal cluster units: evidences of dual emission.
K. Costuas, A. Garreau, A. Bulou, B. Fontaine, J. Cuny, R. Gautier, M. Mortier, Y. Molard, J.-L. Duvail, E. Faulques, S. Cordier
Phys. Chem. Chem. Phys., 2015, 17, 28574 - 28585
53) Polarized phosphorescence of isotropic and metal-based clustomesogens dispersed into chiral nematic liquid crystalline films.
S. M. Wood, M. Pré,vô,t, M. Amela-Cortes, S. Cordier, S. J. Elston, Y.Molard, S. M. Morris
Adv. Optical Mater., 2015, 3, 10, 1368 - 1372
52) From mesomorphic phosphine oxide to clustomesogens containing molybdenum and tungsten octahedral cluster cores.
V. Circu, Y. Molard, M. Amela-Cortes, A. Bentaleb, P. Barois, S. Cordier
Angew. Chem. Int. Ed., 2015, 54, 37, 10921-10925
51) Design and integration in electro-optic devices of highly efficient and robust red NIR phosphorescent nematic hybrid liquid crystals containing [Mo6I8(OCOCnF2n+1)6]2- (n = 1, 2, 3) nanoclusters.
M. Prevô,t, M. Amela-Cortes, S. K. Manna, R. Lefort, S. Cordier, H. Folliot, L. Dupont, Y. Molard
Adv. Func. Mater., 2015, 25, 4966 - 4975
50) Electroswitchable red-NIR luminescence of ionic clustomesogen containing nematic liquid crystalline devices
M. Pré,vô,t, M. Amela-Cortes, S. K. Manna, S. Cordier, T. Roisnel, H. Folliot, L. Dupont, Y. Molard
J. Mater. Chem. C, 2015, 3, 5152-5161
49) Tuned Red NIR phosphorescence of polyurethane hybrid composites embedding metallic nanoclusters for oxygen sensing
M. Amela-Cortes, S. Paofai, S. Cordier, H. Folliot, Y. Molard
Chem. Commun., 2015, 51, 8177-8180
48) Supramolecular Solids Built up from Red-Phosphorescent trans-Re6 Cluster Building Blocks: One Pot Synthesis, Crystal Structures and DFT Investigations
R. El Osta, A. Demont, N. Audebrand, Y. Molard, T. T. Nguyen, R. Gautier, K. A. Brylev, Y. V. Mironov, N. G. Naumov, N. Kitamura, S. Cordier
Z. Anorg. Allg. Chem., 2015, 641, 1156-1163
47) From metallic cluster-based ceramics to nematic hybrid liquid crystals: a double supramolecular approach
Nayak,Susanta K., Amela-Cortes, M., Roiland, C., Cordier, S., Molard, Y.
Chem. Commun., 2015, 58, 3774-3777
46) Evaluation of Mo-95 Nuclear Shielding and Chemical Shift of Mo6X14 (2-) Clusters in the Liquid Phase
T. T. Nguyen, J. Jung, X. Trivelli, J. Trebosc, S. Cordier, Y. Molard, L. Le Polles, C. J. Pickard, J. Cuny, R. Gautier
Inorg. Chem. 2015, 54, 7673-7683
45) Inorganic Molybdenum Octahedral Nanosized Cluster Units, Versatile Functional Building Block for Nanoarchitectonics.
Cordier, S., Grasset, F., Molard, Y., Amela-Cortes, M., Boukherroub, R., Ravaine, S., Mortier, M., Ohashi, N., Saito, N., Haneda, H.
J. Inorg. Organomet. Polym. Mater., 2015, 25, 189-204
44) Surface immobilization of Mo6I8 octahedral cluster cores on functionalized amorphous carbon using a pyridine complexation strategy.
C. Godet, S. Ababou-Girard, B. Fabre, Y. Molard, A. B. Fadjie-Djomkam, S. Deputier, M. Guilloux-Viry, S. Cordier
Diamond and Related Materials, 2015, 55, 131-138
43) Advances in the Engineering of Near Infrared Emitting Liquid Crystals and Copolymers, Extended Porous Frameworks, Theranostic Tools and Molecular Junctions Using Tailored Re6 Cluster Building Blocks
S. Cordier, Y. Molard, K. A. Brylev, Y. V. Mironov, F. Grasset, B. Fabre, N. G. Naumov
J. Cluster Sci., 2015, 26, 53-81
42) Hexacyano octahedral metallic clusters as versatile building blocks in the design of extended polymeric framework and clustomesogens.
Amela-Cortes, M., Cordier, S., Naumov, N. G., Meriadec, C., Artzner, F., Molard, Y.
J. Mat. Chem. C., 2014, 2 (46), 9813-9823
41) Voltage driven photoluminescence modulation of hybrid nanomaterial containing liquid crystalline hybridized ZnO nanoparticles.
Neaime, C., Pré,vô,t, M., Amela-Cortes, M., Cî,rcu, V., Grasset, F., Folliot, H., Molard, Y.
Chem. Eur. J. 2014, 20 (42), 17770-13776
40) Thermotropic Luminescent Clustomesogen Showing a Nematic Phase: a Combination of Experiments and Molecular Simulation Tools
M. Amela-Cortes, F. Dorson, M. Pré,vô,t, A. Ghoufi, B. Fontaine, F. Goujon, R. Gautier, V. Cî,rcu, C. Mé,riadec, F. Artzner, H. Folliot, S. Cordier, Y. Molard
Chem. Eur. J., 2014, 20, 8561
39) Deep Red Luminescent Hybrid coPolymer Materials With High Transition Metal Clusters Content
M. Amela-Cortes, A. Garreau,S. Cordier, E. Faulques,J.-L. Duvail, Y. Molard
J. Mater. Chem. C, 2014, 2, 1545
38) Luminescent liquid crystalline materials based on palladium (II) imine derivatives containing the 2-phenylpyridine core
M. Micutz, M. Ilis, T. Staicu, F. Dumitrascu, I. Pasuk, Y. Molard, T. Roisnel, V. Cî,rcu
Dalton Trans., 2014, 43, 1151
37) Enhancement of smectic C mesophase stability by using branched alkyl chains in the auxiliary ligands of luminescent Pt(II) and Pd(II) complexes
M. Ilis, M. Micutz, F. Dumitrascu, I. Pasuk, Y. Molard, T. Roisnel, V. Cî,rcu, Polyhedron, 2014, 69, 31
36) Controlled synthesis and luminescence properties of trans-[Re6S8(CN)4(OH)2-n(H2O)n]n-4 octahedral rhenium(III) cluster units (n = 0, 1 or 2)
A. Y. Ledneva, K A. Brylev, A. I. Smolentsev, Y. V. Mironov, Y. Molard, S. Cordier, N. Kitamura, N. G. Naumov
Polyhedron, 2014, 67, 8, 351-359
35) Synthesis and Crystal Structure of the Azide K4[Re6Sei8(N3)a6],4H2O, Luminescence, Redox, and DFT Investigations of the [Re6Sei8(N3)a6]4- Cluster Unit
A. Gandubert, K. A. Brylev, T. T. Nguyen, N. G. Naumov, N. Kitamura, Y. Molard, R. Gautier and S. Cordier
Z. Anorg Allg. Chem., 2013, 639, 10, 1756-1762
34) Sensitization of Er3+ Infra-red Photoluminescence embedded in an Hybrid Organic-Inorganic Copolymer containing Octahedral Molybdenum Clusters
Y. Molard, C. Labbé,, J. Cardin, S. Cordier
Adv. Func. Mater., 2013, 23, 38, 4821-4825
33) Taking control of the color of light-emitting nanowires
A. Garreau, F. Massuyeau, S. Cordier, Y. Molard, E. Gautron, P. Bertoncini, E. Faulques, J. Wery, B. Humbert, A. Bulou, J.-L. Duvail
ACS Nano, 2013, 7, 4, 2977-2987
32) Crystal Structures of Complexes Trans-[Re6S8(CN)2L4], L = Pyridine or 4-Methylpyridine
A.Yu. Ledneva, N.G. Naumov, A.V. Virovets, S. Cordier, Y. Molard
Russian J. Structural Chem., 2012, 53, 1, 127-131
31) Ionically Self Assembled Clustomesogen with Switchable Magnetic / Luminescence Properties containing [Re6Se8(CN)6]n- (n = 3, 4) anionic clusters
Y. Molard, A. Ledneva, M. Amela-Cortes, V. Cî,rcu, N. G. Naumov, C. Mé,riadec, F. Artzner, S. Cordier
Chem. Mater., 2011, 23, 5122-5130
30) New thiocyanato and azido adducts of the redox-active Fe(eta(5)-C(5)Me(5))(eta(2)-dppe) center: Synthesis and study of the Fe(II) and Fe(III) complexes
Malvolti, F., Trujillo, A., Cador, O., Gendron, F., Costuas, K., Halet, J. F., Bondon, A., Toupet, L., Molard, Y., Cordier, S., Paul, F.
Inorg. Chim. Acta, 2011, 374 (1), 288-301
29) Differential negative resistance in the current-voltage characteristics of a new palladium(II) metallomesogen
C. Rosu, D. Manaila-Maximean, V. Cî,rcu, Y. Molard, T. Roisnel
Liquid Crystals, 2011, 38, 6, 757
28) Liquid crystal properties resulting from synergetic effects between non-mesogenic organic molecules and a one nanometre sized octahedral transition metal cluster
A. S. Mocanu, M. Amela-Cortes,Y. Molard,V. Cî,rcu, S. Cordier
Chem. Commun., 2011, 47, 2056-2058
27) Covalent Anchoring of Re6Sei8 Cluster Cores Monolayers on Modified n- and p-Type Si(111) Surfaces: Effect of Coverage on Electronic Properties
S. Cordier, B. Fabre, Y. Molard, A.-B. Fadjie-Djomkam, N. Tournerie, A. Ledneva, N. G. Naumov, A. Moreac, P. Turban, S. Tricot, S. Ababou-Girard, C. Godet
J. Phys. Chem. C, 2010, 114, 18622-18623
26) Synthesis and Characterization of A(4)[Re(6)Q(8)L(6)]@SiO2 Red-Emitting Silica Nanoparticles Based on Re-6 Metal Atom Clusters (A = Cs or K, Q = S or Se, and L = OH or CN)
T. Aubert, A. Y. Ledneva, F. Grasset, K. Kimoto, N. G. Naumov, Y. Molard, N. Saito, H. Haneda, S. Cordier
Langmuir 2010, 26, 18512-18518
25) Influence of [Mo6Br8F6]2- Cluster Units Inclusion of within the mesoporous solid MIL-101 on hydrogen storage performances
D. Dybtsev, C. Serre, B. Schmitz, M. Hirscher, M. Latroche, P. Llewellyn, S. Cordier, Y. Molard, M. Haouas, F. Taulelle, G. Fé,rey
Langmuir, 2010, 26, 13, 11283-11290
24) Clustomesogens: liquid crystal based transition metal clusters
Y. Molard, F. Dorson, V. Circu, T. Roisnel, F. Artzner, S. Cordier
Angew. Chem. Int. Ed., 2010, 49, 3351-3355
23) Red-NIR Luminescent Hybrid PMMA Containing Covalently Linked Octahedral Rhenium Metallic Clusters
Y. Molard, F. Dorson, K. A. Brylev, M. A. Shestopalov, Y. Le Gal, S. Cordier, Y. V. Mironov, N. Kitamura, C. Perrin
Chem. Eur. J., 2010, 16, 5613-5619
22) Functional silica nanoparticles synthesised by water-in-oil microemulsion processes
T. Aubert, F. Grasset, S. Mornet, E. Duguet, O. Cador, S. Cordier, Y. Molard, V. Demange, M. Mortier, H. Haneda
J. Colloid Interface Sci., 2010, 341, 201-208
21) synthesis and characterisation of magnetic-fluorescent composite colloidal nanostructures
V. Roullier, V. Marchi-Artzner, O. Cador, F. Dorson, S. Cordier, Y. Molard, F. Grasset
Int. J. Nanotechnol., 2010, 7, 46-57
20) Electrochemical and Charge Transport Behaviour of Molybdenum-Based Metallic Cluster Layers Immobilized on Modified n- and p-Type Si(111) Surfaces
B. Fabre, S. Cordier, Y. Molard, C. Perrin, S. Ababou-Girard, C. Godet
J. Phys. Chem. C, 2009, 113, 40, 17437-17446
19) Shining light on supramolecular assemblies
V. Darcos, C.-H. Huang, N. McClenaghan, Y. Molard, J. H. R. Tucker, Y. Vida Pol, E. Perez-Inestrosa, D. M. Bassani
Pure Appl. Chem., 2009, 81, 9, 1677-1685
18) Electronic Effects and Absorbtion Properties of Supramolecular Assemblies Based on TTF-CH=CH-Py Ligands Coordinated to [Mo6Xi8]4+ Cluster Cores (X=Cl, Br, I)
G. Prabusankar, Y. Molard, S. Cordier, S. Gohlen, Y. Le Gal, C. Perrin, S. Kalahal, J. F. Halet, L. Houahab
Eur. J. Inorg. Chem., 2009, 2153-2161
17) Mesomorphic behaviour and TSDC measurements of ortho-metallated palladium(II) and platinum(II) complexes with S,O-donor co-ligands
V. Cî,rcu, D. M?n?il?-Maximean, C. Rosu, M. Ilis, Y. Molard, F. Dumitrascu
Liquid Crystals, 2009, 36, 123-132
16) Self-Assembly of Ambivalent Organic/Inorganic Building Blocks Containing Re6 Metal Atom Cluster: Formation of Honey Comb Hollow Tubular Metal-Organic Frameworks exhibiting luminescent properties.
M. A. Shestopalov, Y. V. Mironov, V. E. Fedorov, Y. Molard, S. Cordier, C. Perrin, A. Perrin
Inorg. Chem., 2009, 1482-1489
15) Selective functionalisation of Re6 Cluster Anionic Units: From Hexa-Hydoxo [Re6Q8(OH)6]4- (Q = S, Se) to neutral trans-[Re6Q8L4L'2] Hybrid Building Blocks
F. Dorson, Y. Molard, S. Cordier, B. Fabre, O. Efremova, D. Rondeau, Y. Mironov, V. Cî,rcu, N. Naumov, C. Perrin
Dalton trans., 2009, 1297-1299
14) Novel nanomaterials based on inorganic molybdenum octahedral clusters.
S. Cordier, F. Dorson, F. Grasset, Y. Molard, B. Fabre, H. Haneda, T. Sasaki, M. Mortier, S. Ababou-Girard, C. Perrin
J. Clust. Sci., 2009, 20, 1, 9-21
13) One pot synthesis and characterization of bi-functional phosphor-magnetic @SiO2 nanoparticles:controlled and structured association of Mo6 cluster units and -Fe2O3 nanocrystals
F. Grasset, F. Dorson, Y. Molard, S. Cordier, V. Demange, C. Perrin, V. Marchi-Artzner, H. Haneda
Chem. Commun., 2008, 4729-4731
12) When "metal atom clusters" meet ZnO Nanocrystals: Novel ((n-C4H9)4N)2Mo6Br14@ZnO hybrid
F. Grasset, Y. Molard, S. Cordier, F. Dorson, M. Mortier, C. Perrin, M. Guilloux-Viry, T. Sasaki, H. Haneda
Adv. Mater., 2008, 20, 9, 1710-1715
11) Design on New M@ZnO Nanocolloids: Synthesis and Shaping", F. Grasset, S. Cordier, Y. Molard, C. Perrin, V. Nazabal, M. Guilloux-Viry, S. Pechev, N. Saito, H. Ryoken, H. Haneda and T. Sasaki
Inter. J. Nanotech., 2008, 5(6-8), 708-721
10) Water-in-Oil Microemulsion Preparation and Characterization of Cs2[Mo6X14]@SiO2 Phosphor Nanoparticles Based on Transition Metal Clusters (X = Cl, Br, and I)
F. Grasset, F. Dorson, S. Cordier, Y. Molard, C. Perrin, A.-M. Marie, T. Sasaki, H. Haneda, Y. Bando, M. Mortier
Adv. Mater., 2008, 20, 1, 143
9) Assembly of Hexamolybdenum Metallic Clusters on Silicon Surfaces
S. Ababou-Girard, S. Cordier, B. Fabre, Y. Molard, C. Perrin
ChemPhysChem, 2007, 8, 2086
8) Structural Effects on the Ground and Excited-state Properties of Photoswitchable Hydrogen-Bonding Receptors
Y. Molard, D. M. Bassani, J.-P. Desvergne, N. Moran, J. H. R. Tucker
J. Org. Chem., 2006, 71, 8523-8531
7) Anion binding tripodal receptors as structural models for the active site of vanadium haloperoxidases and acid phosphatases
S. Tapper, J. A. Littlechild, Y. Molard, I. Prokes, J. H. R. Tucker
Supramol. Chem., 2006, 18, 1, 55-58
6) Selective electrochemical sensing of acidic organic molecules via a novel guest-to-host proton transfer reaction
H. Miyaji, G. Gasser, S. J. Green, Y. Molard, S. M. Strawbridge and J. H. R. Tucker
Chem. Commun, 2005, 42, 5355-5357
5) Photorelease of an Organic Molecule in Solution: Light-Triggered Blockage of a Hydrogen-Bonding Receptor Site
Y. Molard, D. M. Bassani, J.-P. Desvergne, P. N. Horton, M. B. Hursthouse, J. H. R. Tucker
Angew. Chem. Int. Ed., 2005, 44, 7, 1072-1075
4) Surface Organometallic Chemistry of Main Group Elements: Selective Synthesis of Silica Supported [ Si-O-B(C6F5)3]-[HNEt2Ph]+
N. Millot, A. Cox, C. C. Santini, Y. Molard, J.M. Basset
Chem. Eur. J., 2002, 8, 6, 1438-1442
3) Molecular Scaffolds for di-metallic complexation: the synthesis and complexation properties of tetrakis-Terpyridinyl-calix[4]arene
Y. Molard, H. Parrot-Lopez
Tetrahedron Lett., 2002, 43, 6355-6358
2) Novel Synthetic receptors based on para-amino-pyridine ligands coupled to a p-tert-butylcalix[4]arene via amino acid spacers
Y. Molard, H. Parrot-Lopez
Tetrahedron Lett., 2001, 42, 4799-4802
1) Synthesis of calix[4]arene podands bearing two or four histidine or glycine groups at the lower rim. Complexation properties toward cobalt(II) chloride
Y. Molard, C. Bureau, H. Parrot-Lopez, R. Lamartine, J.B. Regnouf de Vains
Tetrahedron Lett., 1999, 40, 6383-6387