CNRS - Université de Rennes 1 Organométalliques et Catalyse : Chimie et Electrochimie Moléculaires Organometallics and Catalysis : Molecular Chemistry and Electrochemistry |
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2001 -> ... Top of the page
82. Reaction of 1,3-diynes with the electron rich
iron complex (h5-C5Me5)(h2-dppe)Fe-Cl.
A new and direct access to the iron butadiynyl complex (h5-C5Me5)(h2-dppe)Fe-C*C-C*C-SiMe3.
Françoise Coat, Patrice Thominot, Claude Lapinte, J. Organomet.
Chem., 2001, xxx, xxx-xxx.
81. A Convenient Synthesis of Bromopentaarylcyclopentadienes Containing Methyl or Fluorine Substituents. Jean-Yves Thépot, Claude Lapinte, J. Organomet. Chem., 2001, 627, 179-188. |
1991 -> 2000 Top of the page
80. Nonlinear Optical Properties of Redox Active
Mono-, Bi- and Trimetallic -Acetylide Complexes Connected Through a Phenyl
Ring in the Cp*(dppe)Fe Series. An example of Electro-Switchable NLO Response.
Tania Weyland, Isabelle Ledoux, Sophie Brasselet, Joseph Zyss, Claude Lapinte,
Organometallics,
2000, 19, 5235-5237.
79. Electron-Rich Piano-stool Iron s-Acetylides bearing a Functional Aryl Group. Synthesis and Characterization of Fe(II) and Fe(III) Complexes. Raphaël Denis, Loïc Toupet, Frédéric Paul, Claude Lapinte, Organometallics, 2000, 19, 4240-4251. 78. Organometallic Mixed-Valence Systems. Two-Center and Three-Center Compounds with meta Connections around a Central Phenylene Ring. Tania Weyland, Karine Costuas, Loic Toupet, Jean-François Halet, Claude Lapinte, Organometallics, 2000, 19, 4228-4239. 77. A "Conjugal" Consanguineous Family of Butadiynediyl-Derived Complexes; Synthesis and Electronic Ground States of Neutral, Radical Cationic, and Dicationic Iron/Rhenium C4 Species. Frédéric Paul, Wayne E. Meyer, Loic Toupet, Haijun Jiao, John. A. Gladysz, Claude Lapinte, J. Amer. Chem. Soc., 2000, 122, 9405-9414. 76. Synthesis of the bis(iron) Carbene Complex [Cp*(dppe)FeC(OMe)CHCHC(OMe)Fe(dppe)Cp*][PF6]2 : A Binuclear Organometallic Compound With a Low-Spin ´ High-spin Interconversion. Valérie Guillaume, Virginie Mahias, Alain Mari, Claude Lapinte, Organometallics, 2000, 19, 1422-1426. 75. Molecular Wires : Synthesis and Properties of the New Mixed-Valence Complex [Cp*(dppe)Fe-C*C-X-C*C-Fe(dppe)Cp*][PF6] (X = 2,5-C4H2S) and Comparison of its Properties With those of the Related all-carbon Bridged Complex (X = -C4-). Sylvie Le Stang, Frédéric Paul, Claude Lapinte, Organometallics, 2000,19, 1035-1043. 74. Synthesis of Novel Symmetrical and Non symmetrical 6-membered Heterocycles with pendant Electron rich Organoiron Substituents. Sylvie Le Stang, Frédéric Paul, Claude Lapinte, Chemistry of Heterocyclic Compounds, 1999, 387, 1207-1218. 73. Redox active organoiron alkynyl centers with a coordination site: an approach toward molecular plugs. Complexation Reactions with (THF)W(CO)5 and (PhCN)2MCl2 (M = Pd, Pt). Sylvie Le Stang, Frédéric Paul, Claude Lapinte, Inorganica Chemica Acta, 1999, 291, 403-425. (Volume chimie du fer). 72. First Synthesis and Spectroscopic Characterization of Isolated Butatrienylidene Complexes of Transition Metals Françoise Coat, Maud Guillemot, Frédéric Paul, and Claude Lapinte, J. Organomet. Chem., 1999, 578, 76-84. 71. New pyridyl-functionalized Organoiron Alkynyl complexes. Easy Access to Polymetallic Architectures Featuring an Electroactive Site by Simple Coordination Reactions. Sylvie Le Stang, Dirk Lenz, Frédéric Paul, Claude Lapinte, J. Organomet. Chem., 1999, 572 / 2, 189-192. 70. Interaction between two magnetic iron(III) centers through the elemental carbon chain in the complex[Cp*(dppe)Fe-C*C-C*C-Fe(dppe)Cp*][PF6]2. Nathalie Le Narvor and Claude Lapinte, C.R.Acad.Sci.Paris, t.1, Sér. IIc, 1998, 745-749. 69. [(Cp*)(dppe)Fe(III)-]+ Units Bridged Through 1,3-Diethynylbenzene and 1,3,5- Triethynylbenzene Spacers : Ferromagnetic Metal-Metal Exchange Interaction. Tania Weyland, Karine Costuas, Alain Mari, Jean-François Halet, and Claude Lapinte, Organometallics, 1998, 17, 5569 - 5579. 68. Organometallic Molecular Wires and Other Nanoscale-sized Devices. An Approach using the Organoiron (dppe)Cp*Fe Building Block. Frédéric Paul, Claude Lapinte, Coord. Chem. Rev., 1998, 178-180, 427-505 (Volume chimie inorganique française). 67. A Four-Oxidation State Family of Coordinated Carbon: First Isolable and Crystallographically Characterized Triradical [M]-C4-[M]3+. Maud Guillemot, Loïc Toupet, Claude Lapinte, Organometallics, 1998, 17 , 1925- 1927. 66. Investigation of the Iron-Carbon Bonding for Alkyl, Alkynyl, Carbene, Vinylidene, and Allenylidene Complexes Using 57Fe Mössbauer Spectroscopy. Valérie Guillaume, Patrice Thominot, Françoise Coat, Alain Mari, Claude Lapinte, J. Organomet. Chem., 1998, 565, 75-80. (Volume M.I. Bruce) 65. Synthesis of h1-Butadienyl Iron Complex upon Coupling of two Organometallic h1- Vinyl Units and Selective Decomplexation at One End. Valérie Guillaume, Virginie Mahias, Claude Lapinte, J. Organomet. Chem., 1998, 554, 203-205. 64. Palladium-Copper catalyzed Coupling of Iron s-Metalla-alkynes with Aryl Halides. An Simple Way to link Electroactive Organoiron Complexes with Aromatic Structures. Raphaël Denis, Tania Weyland, Frédéric Paul, Claude Lapinte, J. Organomet. Chem., 1997, 545-546, 615-618. 63. Elemental Carbon Chain Bridging two Iron Centers: Syntheses and Spectroscopic Properties of Donor-Acceptor [Fe]-C4-[Fe] Complexes Isolated in Two Different Oxidation States. X-ray Crystal Structure of [Cp*(dppe)Fe-C4-Fe(CO)2Cp*]. Françoise Coat, Marie-Andrée Guillevic, Loic Toupet, Frederic Paul, and Claude Lapinte, Organometallics, 1997, 16 , 5988-5998. 62. Bi- and Trimetallic s-Acetylide Complexes Connected through a Phenyl Ring in the Fe(Cp*)(dppe) Series. Tania Weyland, Claude Lapinte, Gilles Frapper, Maria José Calhorda, Jean-François Halet, and Loic Toupet, Organometallics, 1997, 16, 2024-2031. 61. Synthesis of Bridging bis(Methoxycarbene) and bis(alkylidene) Ligands Bridging Two Iron Centers in the Cp*Fe(L1)(L2) series. X-ray Crystal Structure of the Iron Alkylidene [Cp*Fe(dppe)(=C(H)Me][PF6]. Virginie Mahias, Stéphane Cron, Loic Toupet, and Claude Lapinte, Organometallics, 1996, 15, 5399. 60. Conservation sous 100% de CO2 en présence d'un absorbeur d'oxygène pour prolonger la durée de vie de la viande de bovin. Renerre M., Gatellier P., Minard A., Roussel E., Lapinte C., Viandes Prod. Carnés, 1996, 17, 297. 59. Molecular Wire Constituted of a C8 Chain of Elemental Carbon Bridging two Metal Centers: Synthesis and Characterization of [{Fe(h5-C5Me5)(dppe)}2(m-C8)]. Françoise Coat and Claude Lapinte, Organometallics, 1996, 15, 477. 58. Stereospecific Syntheses of Functionalised Iron Alkyl Complexes With a Stereogenic Metal Center From an Iron Formyl Precursor. Marie Andrée Guillevic, Patrik Brégaint, and Claude Lapinte, J. Organomet. Chem., 1996, 514, 157-162. 57. Syntheses and X-ray Crystal Structures of Five- and Six-Coordinated Iron(I) and Iron(II) Complexes With the Same (h5-C5Me5)Fe(dppe) Framework. Paul Hamon, Loïc Toupet, Jean-René Hamon and Claude Lapinte, Organometallics, 1996, 15, 10. 56. Elemental Carbon Chain Bridging two Iron Centers : Syntheses and Spectroscopic Properties of [Cp*(dppe)Fe-C4-FeCp*(dppe)]n+n[PF6]-. X-ray Crystal Structure of the Mixed Valence Complex (n = 1). N. Le Narvor, L. Toupet, and C. Lapinte, J. Am. Chem. Soc., 1995, 117, 7129 - 7138. 55. 1,4- Diethynylbenzene Bridged Fe(Cp*)(dppe) units: Mixed-Valence 35-electron and bis-Iron(III) 34-electron complexes. N. Le Narvor, C. Lapinte, Organometallics, 1995, 14, 634. 54. A Carbene- Iron Chelate Complex as a Source of a Ferraborane Derivative. S. Nlate, P. Guénot, S. Sinbandhit, L. Toupet, C. Lapinte, V. Guerchais. Angew. Chem. Int. Ed. Engl., 1994, 33, 2218. 53. Synthesis, X-ray Crystal Structure and Magnetic properties of the Six-Coordinated Intermediate Spin Iron(II) Complex: [Fe(h5-C5Me5)(h2-dppe)(h1- O=CMe2]+[CF3SO3]-. P. Hamon, L. Toupet, J. - R. Hamon, C. Lapinte, J. Chem. Soc., Chem. Commun., 1994, 931. 52. Multiple Fluxional Processes in Chiral Pentaphenyl-Cyclopentadienyl-Iron Complexes: X-ray Crystal Structure of (C5Ph5)Fe(CO)(PMe3)(HC=O), and the Barriers to Aryl and Tripodal Rotation in (C5Ph5)Fe(CO)(PMe2Ph)C(O)Et. L. Li, A. Decken, B. G. Sayer, M. J. McGlinchey, P. Brégaint, L. Toupet, J.-Y. Thépot, J.-R. Hamon C. Lapinte, Organometallics, 1994, 13, 682. 51. 17-Electron Alkynyl Complexes of Cyclopentadienyliron(III). N. G. Connelly, M. P. Gamasa, J. Gimeno, C. Lapinte, E. Lastra, J. P. Maher, N. Le Narvor, A. L. Rieger, P. H. Rieger, J. Chem. Soc., Dalton Trans. 1993, 2575. 50. Coupling of a 17-electron Vinyl Complex with Chiral Recognition: Synthesis of The Pure Diastereoisomers of The Bridging Bis(carbene) Complex [{Fe(Cp*)(CO)(PMe3)}2(m-=C(OMe)(CH2)2-C(OMe)=)][PF6]2. S. Cron, V. Morvan, C. Lapinte, J. Chem. Soc., Chem. Commun., 1993, 1611. 49. Generation of the Iron Methylene [(h5-C5Me5)Fe(CO)2(=CH2)]+X- Through Inner- Sphere vs Outer-Sphere Electron Transfer Processes and Reactivity Towards Sulfur Compounds. J. -Y. Thépot, V. Guerchais, L. Toupet, C. Lapinte, Organometallics, 1993, 12, 4843. 48. A Convenient entry to substituted cationic iron-carbene complexes. S. Nlate, C. Lapinte, V. Guerchais, Organometallics, 1993, 12, 4657-4659. 47. First C4 Bridged Mixed - Valence Fe(II)-Fe(III) Complex Delocalized on the Infrared Time Scale. N. Le Narvor, Claude Lapinte, J. Chem. Soc., Chem. Commun., 1993, 357 - 359. 46. Isolation and Characterization of a Cationic 19-Electron Iron(III) Hydride Complex; Electron Transfer Induced Hydride Migration By Carbon Monoxide at an Iron(III) Centre. P. Hamon, J. - R. Hamon, C. Lapinte, J. Chem. Soc., Chem. Commun., 1992, 1602 - 1603. 45. Regiospecific C=C Protection and Cyclopropanation of Dienes Both Assisted by [(h5-C5Me5)Fe(CO)2]+. V. Guerchais, S. Lévêque, A. Hornfeck, C. Lapinte, S. Sinbandhit Organometallics, 1992, 11, 3956 - 3928. 44. One-Electron Reduction of the Iron Carbene Complexes [Fe(Cp*)(CO)2(=C(OMe)R)]+ (R= H, Me) and Hydrogen Atom vs. Alkyl Radical Transfer in the 19-electron Intermediates. S. Nlate, V. Guerchais, C. Lapinte, J. Organomet. Chem., 1992, 434, 89 - 96. 43. Novel Diamagnetic and Paramagnetic Iron(II), Iron(III), and Iron(IV) Classical and Nonclassical Hydrides. The X-Ray Crystal Structure of [Fe(C5Me5)(dppe)D]PF6. P. Hamon, L. Toupet, J. - R. Hamon, C. Lapinte, Organometallics, 1992, 11, 1429 - 1431. 42. Synthesis of Molybdenum Hydride Complexes via Electron Transfer Mechanism and CO Exchange by Phosphine in the 17-electron Intermediates. M. - J. Tudoret, M. - L. Robo, C. Lapinte, Organometallics, 1992, 11, 1419 - 1422. 41. Stereochemical properties of Fe(h5-C5Ph5)(CO)(PR3)R' Complexes (PR3= PMe3, PMe3Ph; R'= Br, C3H3, C(O)C3H5 and CHO) and Steric Inhibition of Tripodal Rotation. P. Brégaint, J. - R. Hamon, C. Lapinte, Organometallics, 1992, 11, 1417 - 1419. 40. Synthesis and characterization of the chiral iron methoxycarbene [Fe(C5Me5)(PMePh2)(CHOMe)][SO3CF3]. M.- J. Tudoret, V. Guerchais, C. Lapinte, J. Organomet. Chem., 1991, 414, 373. 39. Halide and Alkyl (Pentamethylcyclopentadienyl)(dppe) 17-electron Iron(III) Complexes: Synthesis, N.M.R., Magnetic Properties and EHMO Calculations. C. Roger, P. Hamon, L. Toupet, H. Rabaâ, J.-Y. Saillard., J.- R. Hamon, C. Lapinte, Organometallics, 1991, 10, 1045. 38. Sonochemically Promoted Access to New Iron Pentaphenylcyclopentadienyl Cationic Complexes. P. Brégaint, J.- R. Hamon and C. Lapinte, J. Organomet. Chem., 1990, 398, C25. 37. Synthesis of Alkene and Alkyne Pentamethylcyclopentadienyl Dicarbonyl Iron Complexes via the Aquo Derivative [Fe(h-C5Me5)(CO)2(OH2)]+BF4-; Crystal Structure of the Ruthenium Analogue. T. Abdelgani, V. Guerchais, L. Toupet, C. Lapinte, J. Organomet. Chem., 1990, 381, C47. |
1981 -> 1990 Top of the page
36.S-Alkylation of a-Thioether
Iron Compounds by [Ph3C]+ and [Fe(h-C5Me5)(CO)2(CH2)]+.
V. Guerchais, J.-Y. Thépot, C. Lapinte, J. Chem. Soc., Chem. Commun., 1989, 1554. 35. Synthesis and Characterization of a stable Iron Methylene Complexe; Methylene Activation by Electron Transfer Catalysis (E.T.C.). C. Roger, C. Lapinte, J. Chem. Soc., Chem. Commun., 1989, 1598. 34. Synthesis and Electrophilic Properties of Neutral Molybdenum Formyl Complexes Mo(C5Me5)(CO)2(PR3)CHO : Access to Secondary Heterocarbene Compounds. A. Asdar, C. Lapinte, Organometallics, 1989, 8, 2708. 33. Rapid and Convenient Sonochemically Assisted Metal Alkyl Synthesis. C. Roger, M.-J. Tudoret, V. Guerchais, C. Lapinte, J. Organomet. Chem., 1989, 365, 347. 32. a-Hydride Abstraction via a three- step Pathway : Accessto the Electron Rich Iron Methoxycarbene complex [Fe(C5Me5)(P,P'-Ph2CH2CH2PPh2)(=CHOMe)]+PF6-. C.Roger, L. Toupet, C. Lapinte, J. Chem. Soc., Chem. Commun., 1988, 713. 31. Cationic (pentamethylcyclopentadienyl) molybdenum complexes : improved synthesis and characterization . A. Asdar, M.-J. Tudoret, C. Lapinte, J. Organomet. Chem., 1988, 353, 349. 30. NaBH4 Reduction of CO in the Cationic Iron Carbonyl Complexes [(C5Me5)Fe(CO)2L]+PF6-, L = CO or Phosphine C. Lapinte, D. Catheline, D. Astruc, Organometallics, 1988, 7, 1683. 29. Secondary Methoxycarbene Complexes [(C5Me5)M(CO)2(CHOMe)]+ ; (M= Fe, Ru) : Dynamic NMR Studies and Electrophilic properties. V. Guerchais, C. Lapinte, J.-Y. Thépot, L. Toupet, Organometallics, 1988, 7, 604. 28. Direct and Specific Access to Fe(C5Me5) (dppe)X,
(X = Cl,H) promoted by sonochemical Activation.
27. Synthesis Characterization and Reactivity of the neutral Formyl (h-C5Me5)(CO)2(PPh3)MoCHO. New Access to Monocationic Secondary Alkoxycarbene Complexes [(h-C5Me5)(CO)2(PPh3)Mo=CHOE]+X- (E = H, Me). A. Asdar, C. Lapinte, J. Organomet. Chem., 1987, C33, 327. 26. Synclinal and anticlinal isomers of the iron methoxycarbene complex [(h5-C5Me5)Fe(CO)2(=CHOMe)]+; access to functional compounds. V. Guerchais, C. Lapinte, J. Chem. Soc., Chem. Commun., 1986, 894 . 25. Spectroscopic characterization of Unstabilized Electrophilic Iron-methylene and Iron- hydroxymethylene complexes [(n5-C5Me5)Fe(CO)2L]+ (L = CH2 or CHOH). Hydride abstraction versus E.T. mechanism. V. Guerchais, C. Lapinte, J. Chem. Soc., Chem. Commun., 1986, 663 . 24. Complexe fer-hydroxyméthylène: un intermédiaire dans la réduction par étape de CO coordiné. D. Catheline, C. Lapinte, D. Astruc, C.R. Acad. Sc. Paris, 301, série II, 1985, 479. 23. Complexe homobinucléaire du cuivre à pont di-m-hydroxo. Propriétés éléctrochimiques et spectroscopiques des espèces Cu(II)-Cu(II) et Cu(II)-Cu(I). G. Meyer, L. Nadjo, C. Lapinte, Nouveau Journal de Chimie, 1984, 777 . 22. Propriétés électrochimiques, spectroscopiques et catalytiques d'un complexe à valence mixte homobinucléaire Cu(II) -Cu(I). C. Lapinte, Bull. Soc. Sc. Bretagne, 1984 , 36, 56. 21. Reaction of Nucleophiles with the Iron-Arene Complexes (h6-C6R6)2Fe++ and (h5-C6R6H)(h6-C6R6)Fe+ (R = H, Me) and Functionalization of a single Arene Ligand using Hydride as a Protecting Group. A.M. Madonik, D. Mandon, P. Michaud, C. Lapinte, D. Astruc, J. Am. Chem. Soc., 1984, 106 , 3381. 20. Electron Transfer vs. Hydride Transfer in the Reduction of [(C5R5)Fe(dppe)(CO)]+[PF6]- (R= H or CH3) by LiAlH4. C. Lapinte, D. Catheline, D. Astruc, Organometallics, 1984, 3, 817 . 19. Intermolecular Reduction of CO by Iron and Molybdenum Hydrides. C. Lapinte, D. Astruc, J. Organomet. Chem., 1984, 260, C13, 18. Propriétés spectroscopiques et activité catalytique d'un complexe à valence mixte homobinucléaire CuII-CuI. C. Lapinte, G. Meyer, L. Nadjo, H. Rivière, Nouveau Journal de chimie, 1984, 165 . 17. Stepwise Reduction of Iron(II) co-ordinated CO by NaBH4. Access to New Hydroxymethyl and Hydride Complexes. C. Lapinte, D. Astruc, J. Chem. Soc., Commun., 1983, 430. 16. Organometallic Electron-, H-Atom-, and Hydride Reservoirs. Single Electron or H-Atom Transfers in the Reduction of Iron Sandwich Complexes by Hydrides of H2/Pd/C. Reduction of Isolobal Carbonyl Complexes, a Model system for the Fisher-Tropsch synthesis. P. Michaud, C. Lapinte, D. Astruc, Annals New-York Academy of Sciences, 1983, 97. 15. Copper catalysed oxidation of Ascorbic Acid: Versatile role of ligands. Kinetic and spectroscopic studies (U.V.-E.P.R.). C. Fabre, C. Lapinte, Nouveau Journal de Chimie, 1983, 123 . 14. Molecular Oxygen Oxidation of Carbonyl Compounds by Di-m-Hydroxo Homobinuclear Copper (II) Complexes. C. Jallabert, C. Lapinte, H. Rivière, C. Fabre, J. Mol. Catal., 1982, 75 . 13. Role of a Copper Complex in an Oxygen-atom Transfer. Reaction from Dioxygen to Triphenylphosphine. C. Lapinte, H. Riviére, A. Roselli, C. Fabre, J. Chem. Soc., Chem. Commun., 1981, 1109 .
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1972 -> 1980 Top of the page
12. Catalyse micellaire.
C. Lapinte, P. Viout, Techniques de l'Ingénieur, 1980, J 1190 . 11. Molecular oxygen activation by Cu(I) (1-10-phenanthroline). Nature and chemical properties of some isolated complexes. C. Jallabert, C. Lapinte, H. Rivière, J. Mol. Catal., 1980, 127 . 10. Catalyse micellaire. I. Etude de la réactivité en milieu micellaire à l'aide de réactions compétitives. C. Lapinte, P. Viout, Tetrahedron , 1979, 1931 . 9. Structure of Lactate deshydrogenase inhibitor formed from coenzyme. J.F. Biellmann, C. Lapinte, E. Haid, G. Weimann, Biochemistry, 1979, 1212 . 8. Structure of Dimers of NaD+ and of N- Benzyl nicotinamide chloride. J.F. Biellmann, C. Lapinte, Tetrahedron Lett., 1978, 683 . 7. Effets micellaires sur la réaction d'oxydation des oléfines par le palladium. C. Lapinte, H. Rivière, Tetrahedron Lett., 1977, 3817 . 6. Etude des effets des micelles cationiques sur l'état initial et l'état de transition de réactions nucléophiles anioniques. C. Lapinte, P. Viout, Tetrahedron Lett., 1974, 3439 . 5. Influence de la nature de l'anion sur la catalyse micellaire des réactions nucléophiles anioniques. C. Lapinte, P. Viout, Tetrahedron Lett., 1974, 2401. 4. Interprétation de l'exaltation de l'effet catalytique des micelles cationiques par un groupe hydroxyle en b de l'azote. V. Gani, C. Lapinte, P. Viout, Tetrahedron Lett., 1973, 4435 . 3. Interprétation de l'effet des micelles cationiques sur les réactions d'hydrolyse basique, par comparaison avec l'effet du DMSO. V. Gani, C. Lapinte, P. Viout, Tetrahedron Lett., 1973, 2775 . 2. Effet des micelles cationiques sur les vitesses relatives de réactions compétitives du type substitution-élimination. C. Lapinte, P. Viout, Tetrahedron Lett., 1973, 1113 . 1. Influence des micelles sur les vitesses relatives des réactions compétitives du type SN1 et SN2. C. Lapinte et P. Viout, Tetrahedron Lett., 1972, 4221 .
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